Samuel Fisher Bradford Rembrandt Peale (1778-1860)

The picture has something of this: portrait, people, man, wear, neckwear, outerwear, facial expression, jacket, leader, woman, pensive, business, cravat, tie, actor, face.
Perhaps it’s a close up of a painting of a man in a black coat and white collared shirt with a mountain range in the distance in the background.